Mini Review: Tris(dibenzylideneacetone)dipalladium: New Life of the Old Synthon for Pd(0) atom

Received: March 27, 2018; accepted: May 31, 2018

Autores/as

  • Natalya Abramova A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
  • Viacheslav Sokolov A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Resumen

The history of a unique stable and soluble complex Pd2(dba)3 has been considered starting with the classical oxidative addition and finishing by the modern synthesis of Pd nanoclusters catalysts absorbed on the carbon and non-carbon polymer supports. Coordinatively non-saturated Pd(0) particles are used for constructing nanopalladium clusters immobilised which are active as catalysts in the cross-coupling reactions.

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Biografía del autor/a

  • Natalya Abramova, A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

    Dr. Natalya V. Abramova graduated from the Moscow Institute of Fine Chemical Technology. She has been postgraduate student and got PhD degree in the Institute of Organoelement Compounds Russian Academy of Sciences in Moscow. At present she is working in the area of nanocarbon including chemistry of fullerenes, carbon nanotubes, and related objects. She is investigating the novel method of preparing heterogeneous nanopalladium catalysts for the carbon-coupling reactions.

  • Viacheslav Sokolov, A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

    Professor Viacheslav I. Sokolov is the head of the Laboratory of Organometallic Stereochemistry in the Institute of Organoelement Compounds Russian Academy of Sciences in Moscow. He has graduated from Chemistry Department of Moscow University. During his scientific career he has published around 400 papers in peer-reviewed journals in organic, organometallic, or inorganic chemistry. For 20 years he was been a Member of the Editorial board of the Journal of Organometallic Chemistry.

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Publicado

2018-06-10

Número

Vol. 6 Núm. 1 (2018)

Sección

Artículos

Cómo citar

Mini Review: Tris(dibenzylideneacetone)dipalladium: New Life of the Old Synthon for Pd(0) atom: Received: March 27, 2018; accepted: May 31, 2018. (2018). Communications in Inorganic Synthesis, 6(1). https://archivorevistas.usach.cl/index.php/Inorganic/article/view/3221