Synthesis, characterization and 2,5-pyridinedicarboxylic acid interaction of Zinc(II) complexes with N-(4-X-phenyl)pyridine-2-yl-methanimine ligands (X= -Cl and -N(CH3)2)

Autores/as

  • Nicole Dinamarca
  • Manuel Azocar Dr. M. Ignacio Azocar G. http://bioinorganicausach.wordpress.com Facultad de Química y Biología SMAT-C Universidad de Santiago de Chile Fono. 56-022-7183423
  • Pedro Levin
  • Hugo Muñoz

DOI:

https://doi.org/10.21060/cis.v5i2.2692

Resumen

Abstract: Two new Zn(II) N-(4-X-phenyl)pyridine-2-yl-methanimine complexes, [Zn(NN´-Cl)Cl2](1) and [Zn(NN´-N(CH3)2)Cl2](2), have been synthesized and characterized by elemental analysis, FT-IR and NMR-1H spectra. The crystal structure of complex 1 was determined by X-ray single crystal diffraction. Experiments performed by Benesi-Hilderbrand method indicate that zinc complexes interact with 2,5-pyridinedicarboxyc acid.

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Publicado

2017-11-13

Número

Vol. 5 Núm. 2 (2017)

Sección

Artículos

Cómo citar

Synthesis, characterization and 2,5-pyridinedicarboxylic acid interaction of Zinc(II) complexes with N-(4-X-phenyl)pyridine-2-yl-methanimine ligands (X= -Cl and -N(CH3)2). (2017). Communications in Inorganic Synthesis, 5(2). https://doi.org/10.21060/cis.v5i2.2692