Design, synthesis, structural, and spectra characterize of Metal (II) Formate complexes [M(O2CH)2]•n(Solvent) (M =Mn, Cu)

Authors

  • Si Yue Wei, Feng Ying Bai, Ge Song, Ya Nan Hou, Xue Ting Xu, Xiao Xi Zhang, Huan Zhi Zhang, Yong Heng Xing

DOI:

https://doi.org/10.21060/cis.v2i1.1457

Abstract

Formate anion is the simplest carboxylate, compared with other carboxylate, it owns more excellent coordination ability. We used M(OAc)2·n H2O (M=Mn, Cu) as a raw starting material, hydrothermal synthesis methods assisted byDMF hydrolysis which produced the formyl were adopted to prepare metal(II) formates complexes, Mn(HCOO)3·NH2(CH3)2 (1) and Cu(HCOO)3·H3C2O3 (2). The as-prepared products were characterized by elemental analysis, IR spectroscopy, X-ray single-crystal, powder diffraction and thermogravimetric analysis. Structural analysis shows that complex 1 is three-dimensional grid shapes, and complex 2 is a 1D chain structure.

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Issue

Vol. 2 No. 1 (2014)

Section

Artículos

How to Cite

Design, synthesis, structural, and spectra characterize of Metal (II) Formate complexes [M(O2CH)2]•n(Solvent) (M =Mn, Cu). (2014). Communications in Inorganic Synthesis, 2(1). https://doi.org/10.21060/cis.v2i1.1457